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Stabilization of Aqueous Graphene Oxide with Acetone under γ-Ray/UV

丙酮稳定伽玛射线/紫外辐照下的水性氧化石墨烯(英文)
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摘要 Graphene oxide(GO)is a kind of water soluble two-dimensional materials containing a large amount of oxygen-containing groups which infuse GO with water solubility,biocompatibility and functionality,etc.But GO can be easily reduced by losing oxygen-containing groups under some circumstances such as irradiation of-ray or ultraviolet(UV).In this work,we found that acetone can significantly slow down the reduction process of GO under the irradiation of either-ray or UV,which was supported by analysis results with UV-visible(UV-Vis)absorption spectra,X-ray photoelectron spectroscopy,etc.Acetone can capture and remove strongly reducible hydrated electrons generated under-irradiation.GO reduction by UV also involves electron transfer process which can be affected by the presence of acetone.Hence,acetone can be used to stabilize,adjust the radiation reduction process of GO.This would be interesting not only in radiation and radiation protection,but also in understanding the redox properties of GO.
作者 Hong Qin Qin-yi Zhu He-wen Liu 秦洪;祝沁易;刘和文(中国科学技术大学高分子科学与工程系中国科学院软物质化学重点实验室)
出处 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2018年第5期684-690,736,共8页 化学物理学报(英文)
基金 supported by the National Natural Science Foundation of China (No.51673181)
关键词 Graphene oxide ACETONE γ-Ray/UV Reduction 氧化石墨烯 氧化还原 辐射 稳定 丙酮
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