摘要
螺旋聚合物是化学家研究的热点之一.单手性螺旋聚醚作为螺旋聚合物中的一大类,近十余年来引起人们的广泛关注.介绍在手性环氧丙烷3号位碳上引进大位阻基团,通过阴离子聚合合成单手性螺旋聚醚,并介绍其在手性识别、不对称催化等方面的应用研究.
The helical-polymers is one of the hot research topics to the chemists.Single-handed helical polyether is a kind of spiral polymers,which has attracted much attention in past decade.In this review,the single-handed helical polyether with a bulky group at the3-position carbon of chiral epoxide derivatives synthesized by anionic polymerization,was introduced.On the other hand,its potential application,such as chiral recognition,asymmetric catalysis,was presented.
作者
孙允凯
王梦蝶
王小峰
SUN Yunkai;WANG Mengdie;WANG Xiaofeng(School of Chemistry and Chemical Engineering,University of South China,Hengyang,Hunan 421001,China)
出处
《南华大学学报（自然科学版）》
2018年第6期52-59,共8页
Journal of University of South China：Science and Technology
基金
国家自然科学基金项目(11305086)
湖南省自然科学基金项目(14JJ6021)
大学生研究性学习和创新性实验计划资助项目(316)
关键词
螺旋聚醚
环氧化合物
阴离子聚合
不对称催化
helical polyether
epoxide
anionic polymerization
asymmetric catalysis
