摘要
采用普通溶液法合成了配位聚合物Ni(py)_2(CH_3COO)_2(H_2O)_2。利用X-射线单晶衍射对配合物进行了测定,结果表明,配合物属单斜晶系,空间群P2(1)/c,a=8.8434(7)nm,b=11.7457(9)nm,c=7.5726(5)nm,β=106.936(3)°,V=0.75247(10)nm^3,R=0.0605, wR=0.1824。配合物通过分子间氢键作用形成一个一维链状结构。
The metal complex Ni(py)2(CH3COO)2(H2O)2 has been synthesized through a common solution method and measured by single-crystal X-ray diffraction.The finding shows that the complex belongs to monoclinic system with space group P2(1)/c,a=8.8434(7)nm,b=11.7457(9)nm,c=7.5726(5)nm,β=106.936(3)°,V=0.75247(10)nm3,R=0.0605,wR=0.1824.The complex forms a one-dimensional chain structure through intermolecular hydrogen bonding.
作者
牛学丽
刘志
杨华
NIU Xue-li;LIU Zhi;YANG Hua(Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology,Liaocheng University,Liaocheng,Shandong 252059,China;Department of Chemical Engineering,Jincheng Institute of Technology,Jincheng,Shanxi 048026,China)
出处
《晋城职业技术学院学报》
2019年第1期69-72,共4页
Journal of Jincheng Institute of Technology
基金
国家自然科学青年基金<3d-4f唑类配体氮杂金属冠醚单分子磁体合成及其光催化分解水制氮性能研究>(项目编号:21701078)
