两个四核钼(Ⅳ)-硫-亚硝基化合物的合成、结构和电化学性能（英文）

Syntheses, Structures and Electrochemical Properties of Two Tetranuclear Molybdenum(Ⅳ) Sulfur Nitrosyl Complexes

以四水合钼酸铵、硫氰酸铵作为原料在水溶液进行反应,加入盐酸羟胺为还原剂,得到一种可能含有MoNO结构的分子碎片,再进一步与加入多硫化胺溶液的反应,从而分离出两个四核钼(IV)化合物(NH4)_4[Mo_4(m_4-S)(m_3-S)_2(m-S_2)4(h_2-S_2)(NO)_4]·4H_2O(1)和(NH_4)_4[Mo_4(m_4-O)(m-S_2)_6(NO)_4](2),通过UV-3000紫外分光光度计和FTS-40红外分光光度计对这两种配合物进行谱学表征,结果表明这两种配合物中含有亚硝基基团,采用X射线单晶衍射仪对这两种配合物的结构测定,并对其电化学特性进行了进一步的研究。

Reactions of ammonium molybdate tetrahydrate,ammonium thiocyanate,and hydroxylammonium chloride as a reducing agent in aqueous solution probably afforded a specie containing the Mo N O fragment,which was further treated with ammonium polysulfide to result in isolation of two tetranuclear molybdenum(IV)sulfur nitrosyl complexes(NH4)4[Mo4(m4-S)(m3-S)2(m-S2)4(h2-S2)(NO)4]·4H2O(1)and(NH4)4[Mo4(m4-O)(m-S2)6(NO)4](2).Two tetranuclear molybdenum(IV)complexes were characterized spectroscopically by ultraviolet spectrophotometer UV-3000 and infrared spectrophotometer FTS-40,and their structures were determined by single-crystal X ray diffraction,the results show that the two complexes containe nitrosyl group,their electrochemical properties were also investigated.