摘要
通过Co(Ac)_2与四(对甲氧基苯基)卟啉配体(TMPP)作用,合成四(对甲氧基苯基)卟啉钴(CoTMPP),利用IR、紫外-可见光谱及~1 H-NMR对其进行了表征,并用紫外-可见光谱研究了CoTMPP与NO、CO_2、SO_2、H_2S的识别作用.研究发现:室温下,CoTMPP能选择性的吸收NO气体分子,不与CO_2、SO_2、H_2S气体作用,可对有毒气体NO进行识别和检测,能够有选择性的捕集烟道气中的NO.
4(p-methoxyphenyl) porphyrin cobalt (CoTMPP) has been synthesized by the reaction betweenCo(Ac)and 4(p-methoxyphenyl) porphyrin (TMPP) ligands. The CoTMPP is characterized by means of IR,UV-visible and 1H-NMR. Moreover,the CoTMPP interaction with NO (CO2,SO2, H2S) was studied by UV-visible spectrum at room temperature,result show that there is a selective recognition reaction between CoTMPP and NO. The result of this study will play an important role in the identification and detection of toxic gas NO?and there will be potential applications in NO selective capture in flue gas.
作者
冶杰慧
任帅伟
张建斌
于梦然
张桂峰
YE Jie-hui;REN Shuai-Wti;ZHANG Jian-bin;YU Meng-ran;ZHANG Gui-feng(College of Chemical Engineering , Inner Mongolia University of Technology , Hohhot 010051 ,China;Inner Mongolia Engineering Research Center for CO2 Capture and Utilization ,Hohhot 010051 ,China)
出处
《内蒙古工业大学学报（自然科学版）》
2018年第5期346-349,共4页
Journal of Inner Mongolia University of Technology：Natural Science Edition
基金
内蒙古教育厅项目(NJZY18089)
内蒙古工业大学科学研究项目(ZD201604)
内蒙古自治区级大学生创新创业训练计划项目(201610128006)
