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Degradation of benzothiophene in diesel oil by LaZnAl layered double hydroxide: photocatalytic performance and mechanism 被引量:2

Degradation of benzothiophene in diesel oil by LaZnAl layered double hydroxide: photocatalytic performance and mechanism
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摘要 A new type of photocatalytic La^(3+)–Zn^(2+)–Al^(3+)–MoO_4^(2-) layered double hydroxide(LDH) material(molar ratio, La/Zn/Al = 1:7:2) was prepared by a complexing agent-assisted homogeneous precipitation technique. The structure of the prepared LDH material was systematically studied. Under UV irradiation, the desulfurization efficiency of the LDH material was 87% in 2 h. For La^(3+)–Zn^(2+)–Al^(3+)–MoO_4^(2-) LDH material, the introduction of MoO_4^(2-) increased the interlayer space for promoting the adsorption of benzothiophene(BT), and MoO_4^(2-) might provide active sites for the oxidation of BT, resulting in the high desulfurization efficiency. A new type of photocatalytic La^(3+)–Zn^(2+)–Al^(3+)–MoO_4^(2-) layered double hydroxide(LDH) material(molar ratio, La/Zn/Al = 1:7:2) was prepared by a complexing agent-assisted homogeneous precipitation technique. The structure of the prepared LDH material was systematically studied. Under UV irradiation, the desulfurization efficiency of the LDH material was 87% in 2 h. For La^(3+)–Zn^(2+)–Al^(3+)–MoO_4^(2-) LDH material, the introduction of MoO_4^(2-) increased the interlayer space for promoting the adsorption of benzothiophene(BT), and MoO_4^(2-) might provide active sites for the oxidation of BT, resulting in the high desulfurization efficiency.
出处 《Petroleum Science》 SCIE CAS CSCD 2019年第1期173-179,共7页 石油科学(英文版)
关键词 LDH HOMOGENEOUS precipitation PHOTOCATALYTIC activities CATALYTIC oxidation MECHANISM LDH Homogeneous precipitation Photocatalytic activities Catalytic oxidation mechanism
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