Cationic and anionic energetic materials based on a new amphotère 被引量：2

基于一个新两性化合物的阳离子和阴离子含能材料（英文）

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摘要本文报道了5,5?-二氨基-4,4?-二硝氨基-3,3?-双-1,2,4-三唑(1)的第一种阳离子形式及其合成和表征.化合物1与硝酸反应生成了5,与RDX相比,这是一种具有更高的分解温度和更好爆轰性能的炸药,与HMX相比其感度更低. 1的阴离子作为配体和钾离子的自组装合成了起爆药4,与目前广泛使用的Pb(N3)2相比较,它的性能更加优异.两性化合物1的两个衍生物的分离具有重要意义:(1)说明了化合物1的两性性质;(2)开启了它们作为有前景的含能前体的研究,为更多含能离子盐的合成提供参考.

作者 Yuangang Xu Pengcheng Wang Qiuhan Lin Yao Du Ming Lu 许元刚;王鹏程;林秋汉;杜耀;陆明(School of Chemical Engineering, Nanjing University of Science and Technology;School of Materials Science & Engineering, Beijing Institute of Technology)

机构地区 School of Chemical Engineering School of Materials Science & Engineering

出处《Science China Materials》 SCIE EI CSCD 2019年第5期751-758,共8页 中国科学（材料科学（英文版）

基金 financially supported by the joint fund of the National Natural Science Foundation of China and China Academy of Engineering Physics (NSAF, U1530101)

关键词 amphoteres HYDROXIDES of ALUMINUM SIGNIFICANT progresses

分类号 TB [一般工业技术]

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Science China Materials

2019年第5期

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Cationic and anionic energetic materials based on a new amphotère 被引量：2

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