摘要
介绍了一种复合型FeS清洗剂的研制,其原理为利用配位反应和氧化还原反应来清除设备中的FeS。分别对不同的配位剂和氧化剂的FeS清除效果进行了考察,根据单因素实验结果,选择焦磷酸钠和次氯酸钠作为清洗剂的主要成分,利用正交实验考察了次氯酸钠浓度、焦磷酸钠质量、清洗时间及清洗温度对FeS清除率的影响。结果表明,当次氯酸钠浓度为0.003 mol/L、焦磷酸钠质量为1.5 g、清洗温度为80℃和清洗时间为12 h时,FeS的清除率最高,为75.0%。
Introduces a kind of compound ferrous sulfide cleaner, the principle to use the coordination reaction and oxidation and reduction reaction to the ferrous sulfide removal equipment. Respectively in different complex agent and oxidant ferrous sulfide removal, according to the result of single factor experiments, chose the sodium pyrophosphate and sodium hypochlorite as the main composition of cleaning agent, use the orthogonal experiment to investigate the concentration of sodium hypochlorite, sodium pyrophosphate mass, cleaning time and cleaning temperature effect on the clearance of ferrous sulfide. The experimental results show that when the concentration of sodium hypochlorite is 0.003 mol/L, sodium pyrophosphate mass is 1.5 g, cleaning temperature is 80 ℃ and the time is 12 h, the clearance rate of ferrous sulfide is highest, at 75.0%.
作者
唐明
张振华
李萍
孙秀丽
Tang Ming;Zhang Zhenhua;Li Ping;Sun Xiuli(College of Chemistry,Chemical Engineering and Environmental Engineering,Liaoning Shihua University,Fushun Liaoning 113001,China)
出处
《辽宁石油化工大学学报》
CAS
2019年第2期33-36,共4页
Journal of Liaoning Petrochemical University
基金
中国石油化工集团总公司项目(311061)
关键词
FeS清洗剂
配位反应
氧化还原反应
自燃
Ferrous sulfide
Complexing reaction
Oxidation and eduction reaction
Spontaneous combustion