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Functionalized Polyphosphoester via Living Ring-opening Polymerization and Photochemical Thiol-ene Click Reaction

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摘要 Poly(ethylene phosphonate)was synthesized via the living ring-opening polymerization of cyclic phos-phonate monomer catalyzed by organocatalyst.The pendant vinyl ftmctionalities were employed to perform the pho-tochemical click reactions wi&tMols.We demonstrated that both small thiol molecules and macromolecular thiols could be efficiently coupled into the PPE side chains,enabling the rapid and efficient functionalization of polyphos-phoesters(PPE).
出处 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2019年第2期340-344,共5页 高等学校化学研究(英文版)
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