四重氢键自组装体系的设计与应用

The Design and Application of Quadruple Hydrogen Bonded Systems

氢键是自然界中最基本的分子间弱相互作用力之一,是构筑超分子自组装体系的理想推动力。近年来,构筑性能优良的多重氢键组装体系已经成为超分子化学的一个热门研究领域。其中,四重氢键组装体系因具有较强的结合力、合成简单、结构易于修饰以及可预测的识别性能等优点,在构筑超分子组装体方面得到了广泛应用。本文综述了四重氢键组装体系的研究进展,重点介绍了各类四重氢键体系的设计思路及其应用。

Hydrogen bond is one of the most basic weak interaction of natural intermolecular forces and the ideal driving force for constructing supramolecular self-assembly systems. In the past few years, the construction of excellent multiple hydrogen bonded building blocks has become a hot research direction in supramolecular chemistry. Among that, quadruple hydrogen bonded systems are widely used for the construction of supramolecular assemblies due to their several advantages, such as strong binding power, simple synthesis, easily modifiable structure, and predictable recognition performance. In this review, we aim to provide a broad overview of the progress of quadruple hydrogen bonded systems. More specifically, we emphatically elaborate the design principles and applications of various typed quadruple hydrogen bonded systems.