摘要
The dual-emissive N,S co-doped carbon dots (N,S-CDs) with a long emission wavelength were synthesized via solvothermal method.The N,S-CDs possess relatively high photoluminescence (PL) quantum yield (QY) (35.7%) towards near-infrared fluorescent peak up to 648 nm.With the advanced characterization techniques including X-ray photoelectron spectroscopy (XPS),Fourier transform infrared spectroscopy (FTIR),etc.It is found that the doped N,S elements play an important role in the formation of high QY CDs.The N,S-CDs exist distinct pH-sensitive feature with reversible fluorescence in a good linear relationship with pH values in the range of 1.0-13.0.What is more,N,S-CDs can be used as an ultrasensitive Ag+ probe sensor with the resolution up to 0.4 μM.This finding will expand the application of as prepared N,S-CDs in sensing and environmental fields.
基金
Beijing Nova Program Interdisciplinary Studies Cooperative Project (No. Z181100006218138)
Science Foundation of China University of Petroleum-Beijing (No. 2462018BJC004)
National Key Specialty Construction Project of Clinical Pharmacy (No. 30305030698)
Research Funding of Sichuan Provincial Peoples Hospital (No. 2017LY08) for the support.
