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Strategy for Synthesizing Novel Acetamidines as CO_2-Triggered Switchable Surfactants via Acetimidates

Strategy for Synthesizing Novel Acetamidines as CO_2-Triggered Switchable Surfactants via Acetimidates
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摘要 In this study, we developed a strategy for using the Scoggins procedure in the synthesis of acetamidines as novel C02-triggered switchable surfactants via acetimidates by effectively tuning the chemical equilibrium. The as-synthesized N'-alkyl-N,Ndiethylacetamidines exhibit excellent CO_2/N_2 switchability and their bicarbonate salts have the ability to emulsify oil-water mixtures. In this study, we developed a strategy for using the Scoggins procedure in the synthesis of acetamidines as novel C02-triggered switchable surfactants via acetimidates by effectively tuning the chemical equilibrium. The as-synthesized N'-alkyl-N,Ndiethylacetamidines exhibit excellent CO_2/N_2 switchability and their bicarbonate salts have the ability to emulsify oil-water mixtures.
出处 《Transactions of Tianjin University》 EI CAS 2019年第3期237-244,共8页 天津大学学报(英文版)
基金 supported by the China National Petroleum Corporation (RIPED-2017-JS-87)
关键词 CO2 SWITCHABLE SURFACTANTS Acetimidate Acetamidine Consecutive REACTION CO_2 switchable surfactants Acetimidate Acetamidine Consecutive reaction
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