氧杂环丙烷环加成反应研究进展

Research Progress in the Cycloaddition Reactions of Oxiranes

氧杂环丙烷是一类环内含有氧原子的三元环状化合物,由于其本身的特殊结构和独特性质,它们可与含有各种不饱和键的化合物发生多种环加成反应,以此来制备种类更加丰富的含氧杂环化合物,综述了近年来氧杂环丙烷与含有各种不饱和键的化合物发生的环加成反应的研究进展,主要包括[3+2]、[3+3]和[4+3]等环加成反应,并对其发展方向进行了展望.

Oxiranes are a class of oxygen-containing three-membered cyclic compounds. Due to their distinctive structure and unique properties, they can undergo a variety of cycloaddition reactions with compounds bearing diverse unsaturated bonds. The recent advances in the cycloaddition of oxiranes with this kind of compounds over the past decade, including[3+2],[3+3] and[4+3] are summarized. Moreover, the prospects of future development are also discussed.