摘要
异呋咱涵盖1,3,4-噁二唑和1,2,4-噁二唑,是一类用于构成高能钝感含能材料的基本单元.此类化合物已成为含能材料领域的研究热点之一.概述了两大类异呋咱含能化合物及其含能衍生物的最新研究进展,着重探讨了异呋咱环化反应机理和构建方法,介绍了代表性异呋咱含能化合物的物化和爆轰性能,并对其发展前景进行了展望.
Isofurazan is composed of 1,3,4-oxadiazole and 1,2,4-oxadiazole, and the isofurazan compounds have gained considerable prominence as energetic compounds. This review focues on the two major classes of isofurazan energetic compounds and their energetic derivatives. The cyclization methods and reaction mechanism of isofurazans are presented. Several energetic compounds of isofurazans with excellent performances are highlighted, and their main physicochemical properties and detonation performances and their development prospect are discussed.
作者
薛琪
毕福强
张家荣
张俊林
王伯周
张生勇
Xue Qi;Bi Fuqiang;Zhang Jiarong;Zhang Junlin;Wang Bozhou;Zhang Shengyong(Xi'an Modern Chemistry Research Instritute, Xi'an 710065;State Key Laboratory of Fluorine & Nitrogen Chemical, Xi'an 710065;School of Pharmacy, Fourth Military Medical University, Xi'an 710032)
出处
《有机化学》
SCIE
CAS
CSCD
北大核心
2019年第5期1244-1262,共19页
Chinese Journal of Organic Chemistry
基金
国家自然科学基金(No.21243007)资助项目~~
关键词
异呋咱
含能化合物
合成
爆轰性能
isofurazan
energetic compound
synthesis
detonation performances
