摘要
Lithium sulfur battery has been identified as a promising candidate for next storage devices attributing to ultrahigh energy density.However,non-conductive nature of sulfur and shuttling effect of soluble lithium polysulfides are intractable remaining problems.Herein,we develop a highly conductive nickel-rich Ni12P5/CNTs hybrid with high specific surface area as sulfur host to address these issues.The polar nature of Ni12Ps/CNTs can significantly relieve the shuttle effect by means of a strong affinity towards lithium polysulfides and enhance kinetics of polysulfides redox reactions.In addition,the Ni12P5/CNTs with a superior conductivity (500 S·m^-1) and high surface area of 395 m^2·g^-1 enables the effective electron transfer and expedited interfacial reaction.As a result,Ni12P5/CNTs hosted sulfur cathode exhibits high rate capability (784 mAh·g^-1 at 4 C) and stable cycling performance with a negligible capacity fading of 0.057 % per cycle over 1,000 cycles at 0.5 C.This work paves an alternative way for designing high performance sulfur cathodes involved metal-rich phosphides.
基金
the National Natural Science Foundation of China (Nos.21776041 and 21875028)
Cheung Kong Scholars Programme of China (No.T2015036).