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功能化石墨烯/聚甲基丙烯酸甲酯复合材料的制备及介电性能研究

Preparation and dielectic properties of functionalized graphene/polymethyl methacrylate composites
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摘要 利用原位聚合的方法制备了不同添加量1,3-二羰基功能化还原氧化石墨烯(rDGO)和聚甲基丙烯酸甲酯(PMMA)的复合材料(rDGO/PMMA).通过傅里叶变换红外光谱和场发射扫描电镜等对功能化石墨烯rDGO与rDGO/PMMA复合材料的官能团和微观结构进行了表征.并对它的亲水性和介电性能进行了测试,rDGO/PMMA复合薄膜比纯的PMMA膜在亲水性和介电性能上均有提高.结果表明:rDGO/PMMA复合材料有望在未来介电存储设备上得到应用. A novel and facile method was proposed to synthesize high-quality 1,3-dicarbonyl-functionalized reduced graphene oxide(rDGO)and polymethyl methacrylate(PMMA)composite(rDGO/PMMA)films by means of in-situ polymerization of rDGO and methyl methacrylate in solution.Meanwhile,fourier transform infrared spectroscopy verified the functional groups in the rDGO/PMMA nanocomposites.The field-emission scanning electronmicroscopy was performed to investigate the morphology of rDGO and rDGO/PMMA composite films.The hydrophilic and electrical characterization properties of rDGO/PMMA composites were investigated by contact angle and dielectric constant.These results indicate that compared with pure PMMA films,the hydrophilicity and dielectric properties of the rDGO/PMMA composite films were improved,which are expected to be used in dielectric storage equipments in the future.
作者 李亚男 邢瑞光 张邦文 LI Yanan;XING Ruiguang;ZHANG Bangwen(Materials and Metallurgy School,Inner Mongolia University of Science and Technology,Baotou 014010,China)
出处 《内蒙古科技大学学报》 CAS 2019年第2期126-130,共5页 Journal of Inner Mongolia University of Science and Technology
基金 内蒙古自治区自然科学基金资助项目(2018LH05020 2018LH02003)
关键词 石墨烯 功能化 聚甲基丙烯酸甲酯 复合材料 介电性能 graphene functionalized polymethyl methacrylate composites dielectic properties
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