手性环戊二烯过渡金属配合物在不对称催化反应中的应用

Application in the Asymmetric Catalytic Reactions of Chiral Cyclopentadienyl-Transition-Metal Complexes

手性环戊二烯配体作为不对称催化反应中的立体控制元素受到金属有机工作者的关注,尤其是设计合成更多通用的手性环戊二烯基配体成为了不对称催化领域的研究中心之一.综述了近年来发展出的各种手性环戊二烯配体与不同过渡金属的配合物,以及这些配合物在催化不对称反应方面的进展.

The chiral Cp ligands as stereocontrolling element of asymmetric catalytic reactions have attracted increasing attention.Particularly,designing and synthesizing more versatile chiral Cp ligands became one of the most interested research focuses in asymmetric catalysis.The complexes of various chiral Cp ligands with different transition metals that advanced in recent years,and the applications of these complexes in catalytic asymmetric reactions are reviewed in this paper.