摘要
将高温煤焦油、催化裂化油浆分别与新疆长焰煤进行共处理实验,考察了实验条件对共处理反应性能的影响。综合分析共处理条件对原料油转化率、油产率、气产率和沥青质产率的影响规律,得到合适的实验条件为:催化剂质量分数1%,重质油与长焰煤质量比2∶1,反应温度450℃,氢初压10MPa,反应时间120min。对煤-油共处理产物进行蒸馏特性分析可知:高温煤焦油共处理产物主要集中在低于230℃馏分,收率为35.14%;催化裂化油浆共处理产物主要集中在170~370℃和370~500℃馏分。
Co-hydrogenation of high temperature coal tar and FCC slurry with Xinjiang long flame coal were carried out.The effects of test conditions on co-treatment reaction performance was investigated.The influences of co-treatment conditions on the feed oil conversion,oil yield,gas yield and asphaltene yield were comprehensively analyzed.The optimized experimental conditions were confirmed as follows: catalyst mass fraction of 1%,ratio of oil to coal of 2 ∶1,reaction temperature of 450 ℃,initial hydrogen pressure of 10 MPa,reaction time of 120 min.The distillation characteristics of co-processing products were analyzed.The products of coal-derived oil are mainly concentrated in fractions of less than 230 ℃ with a yield of 35.14%.The products of FCC slurry are mainly concentrated at 170-370 ℃ and 370-500 ℃,respectively.
作者
胡发亭
李军芳
毛学锋
HU Fating;LI Junfang;MAO Xuefeng(Beijing Research Institute of Coal Chemistry,State Key Laboratory of Coal Mining and Clean Utilization,National Energy Technology and Equipment Laboratory of Coal Utilization and Emission Control,China Coal Research Institute,Beijing 100013,China)
出处
《石油学报(石油加工)》
EI
CAS
CSCD
北大核心
2019年第4期798-806,共9页
Acta Petrolei Sinica(Petroleum Processing Section)
基金
国家重点研发计划基金项目(2018YFB0604601)资助
关键词
催化裂化油浆
高温煤焦油
长焰煤
煤油共加氢
反应性能
fluid catalytic cracking slurry
high temperature coal tar
long flame coal
coal-oil co-processing
reaction performance