新型含氮多孔有机聚合物材料吸附CO2的研究进展

Research Progress on Adsorption of CO2 by New Nitrogen-containing Porous Organic Polymer Materials

含氮有机聚合物材料是一类具有较高比表面积的多孔材料,材料骨架中含有富电子的氮物种,可与二氧化碳产生较强的相互作用,能够显著提高二氧化碳的吸附性能。以含氮多孔有机聚合物材料为基础,介绍了该类聚合物材料的分类、结构、性质和特点以及对二氧化碳的吸附性能,综述了含氮多孔有机聚合物材料在二氧化碳吸附方面的最新进展,探讨了其在吸附应用中存在的问题,展望了含氮多孔有机聚合物材料在吸附二氧化碳方面的发展趋势。

Nitrogen-containing organic polymer material is a kind of porous material with a high specific surface area.The material skeleton contains electronic-rich nitrogen species,which can have a strong interaction with carbon dioxide and can significantly improve the adsorption performance of carbon dioxide.Based on porous nitrogenous organic polymer materials,the classification,structure,properties,characteristics and adsorption performance of carbon dioxide of this kind of polymer materials were introduced.The latest progresses on CO 2 adsorption of nitrogen organic porous polymer materials were reviewed,the problems existing in the applications of adsorption were discussed,and the development trend of porous nitrogenous organic polymer materials in carbon dioxide adsorption was prospected.