细乳液聚合最新研究进展

Recent Progress in Mini-Emulsion Polymerization

随着高分子合成技术的迅速发展,乳液聚合法的发展创新趋势较为明显,其聚合过程对商品聚合物的生产至关重要,所制备出的聚合物乳液可直接用作水性涂料和胶粘剂等。文中具体介绍了细乳液聚合体系的设计方法、聚合过程及稳定机理,重点综述了近年来细乳液聚合在高固含量细乳液制备、纳米复合材料制备(荧光聚合物纳米粒子、有机/无机纳米复合材料)及聚合物空心球或微球制备等方面的研究进展。

With the rapid development of polymer synthesis technology, the development trend of emulsion polymerization is more obvious. Now its polymerization process is more important for the production of commercial available polymers. The emulsion can be directly used for waterborne coatings and adhesives, etc. The preparation technique, polymerization process and stabilization mechanism of mini-emulsion polymerization system were introduced in this paper, focusing on the recent progress of minie-emulsion polymerization in the preparation of high solid content polymer mini-emulsion, nanocomposite (fluorescent polymer nanoparticles, organic/inorganic nanocomposites) and hollow or microspheres polymer was reviewed in this paper.