摘要
通过静电纺丝法制备聚丙烯腈纤维(PANF)并高温碳化以获得碳纳米纤维(CNF),利用水热法将纳米铂(PtNPs)负载于CNF表面得到Pt/CNF复合材料,将其固定于电极表面之后进一步利用电沉积法将纳米金(AuNPs)形成于Pt/CNF表面得到修饰电极(Au/Pt/CNF/CILE)。通过扫描电镜考察复合材料的形貌结构,利用电化学方法研究修饰电极的电化学性能,求解其有效面积。结果表明CNF呈网状结构,PtNPs稳定附着在纤维表面,电沉积的AuNPs均匀分布在Pt/CNF/CILE表面,所制备的修饰电极的导电性能增强、有效面积增大且表面丰富的电活性位点促进了电子的有效转移。
Polyacrylonitrile fiber (PANF) was prepared by electrospinning, and further transformed into carbon nanofiber (CNF) by high temperature carbonization. Then platinum nanoparticles (PtNPs) were loaded on CNF surface by hydrother. mal method to obtain the Pt/CNF composite, which was immobilized on the surface of carbon ionic liquid electrode (CILE). Then gold nanoparticles (AuNPs) were formed on Pt/CNF surface by electrodeposition to construct a modified electrode (Au/ Pt/CNF/CILE). The morphology of nanocomposite was characterized by SEM and the electrochemical properties of modified electrode were investigated by various electrochemical methods with the effective area measured. The results showed that CNF had a spatial network structure with PtNPs successfully loaded, and the formation of AuNPs on Pt/CNF/CILE surface resulted in the increase of the conductivity and effective area, which provided more electroactive sites for the electron trans. fer.
作者
谢慧
黄少梅
曾婷
李翔
李玉华
孙伟
阮承祥
XIE Hui;HUANG Shaomei;ZENG Ting;LI Xiang;LI Yuhua;SUN Wei;RUAN Chengxiang(Key laboratory of functional material and photoelectrochemistry of Haikou,College of Chemistry and Chemical Engineering,Hainan Normal University,Haikou 571158,China;Jiangxi Key Laboratory of Surface Engineering,College of Materials Science and Engineering,Jiangxi Science and Technology Normal University,Nanchang 330013,China)
出处
《海南师范大学学报（自然科学版）》
CAS
2019年第3期237-242,共6页
Journal of Hainan Normal University（Natural Science）
基金
海南省自然科学基金(2017CXTD007)
海口市重点科技计划项目(2017042)
海南省研究生创新研究项目(Hys2018-211)
关键词
碳纳米纤维
纳米铂
纳米金
化学修饰电极
静电纺丝
carbon nanofiber
platinum nanoparticle
gold nanoparticle
chemical modified electrode
electrospinning
