摘要
Here, through the synergism between kinetic dynamic imine-exchange control and thermodynamic control, rarely observed compressible, porous, crystalline covalent organic framework (COF) aerogels were synthesized, the mechanism behind which is a framework crystallization induced self-assembly (FCISA) process. The prepared COF aerogel possessed extremely high BET surface over 2000 m^2·g^-1 and high maximum equilibrium adsorption capacity toward bisphenol-A of 699 mg·g^-1 in aqueous solution.
Here,through the synergism between kinetic dynamic imine-exchange control and thermodynamic control,rarely observed compressible,porous,crystalline covalent organic framework （COF） aerogels were synthesized,the mechanism behind which is a framework crystallization induced self-assembly （FCISA） process.The prepared COF aerogel possessed extremely high BET surface over2000 m2·g-1 and high maximum equilibrium adsorption capacity toward bisphenol-A of 699 mg·g-1 in aqueous solution.
基金
financially supported by the National Natural Science Foundation of China (Nos. 21674068 and 51633004)
