摘要
The crystal and molecular structure of the title complex, Cu（ada）2（py）2（H2O）（ada=adamantanecarboxylic group, py=pyridine）, C 32H 42CuN2O5, were determined by XRD. It belongs to monoclinic system with space group P21/n and crystal cell parameters:a=1.619 9（3）, b=0.680 5（1）, c=2.802 8（6） nm, β=94.15（3）°; V=3.082（1） nm 3, Z=4, Dc=1.289 g/cm3, Mr=589.22, μ（MoKα）=0.750 mm -1, F（000）=1 268. The structure was refined to R=0.057 8 and wR=0.158 1 for 4 447 observed reflections with I≥2σ（I）. The aquo complex is mononuclear with distorted square-pyramidal coordination.
The crystal and molecular structure of the title complex, Cu(ada)_2(py)_2(H_2O)(ada=adamantanecarboxylic group, py=pyridine), C_ 32H_ 42CuN_2O_5, were determined by XRD. It belongs to monoclinic system with space group P2_1/n and crystal cell parameters:a=1.619 9(3), b=0.680 5(1), c=2.802 8(6) nm, β=94.15(3)°; V=3.082(1) nm 3, Z=4, D_c=1.289 g/cm3, M_r=589.22, μ(MoKα)=0.750 mm -1, F(000)=1 268. The structure was refined to R=0.057 8 and wR=0.158 1 for 4 447 observed reflections with I≥2σ(I). The aquo complex is mononuclear with distorted square-pyramidal coordination.
出处
《应用化学》
CAS
CSCD
北大核心
2002年第11期1109-1111,共3页
Chinese Journal of Applied Chemistry
基金
浙江省科学技术厅基金资助项目 (0 12 0 61)
