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ⅢB族金属苯乙酰缩氨基硫脲配合物的合成、表征与抗肿瘤活性 被引量:5

Preparation,Characterization and Antitumor Activity of Sc(Ⅲ),Y(Ⅲ) and La(Ⅲ) Complexes of Acetophenone Thiosemicarbazone
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摘要 合成了 Sc( )、Y ( )、L a( )与苯乙酰缩氨基硫脲形成的 1∶ 2型配合物。元素分析确定其分子式为 :ML2 Cl· n H2 O[M=Sc( ) ,Y( ) ,L a( ) ,n=0~ 5 ],用红外光谱、紫外光谱、核磁共振氢谱对该配合物进行了结构表征 ,研究了其摩尔电导和溶解性能 ,并测试了其抗肿瘤活性。 In this paper three complexes of Sc(Ⅲ),Y(Ⅲ), La(Ⅲ) with acetophenone thiosemicarzone were prepared The elementary analyses revealed that the formula of the complexes was ML 2Cl·nH 2O[M= Sc(Ⅲ),Y(Ⅲ), La(Ⅲ),n=0~5] The structure of the complexes was characterized by IR,UV,H'NMR,DTA-TGA and the molecular conductance Afterwards,the antitumor activity of the complex of Y(Ⅲ) was tested
出处 《稀土》 EI CAS CSCD 北大核心 2002年第5期14-17,共4页 Chinese Rare Earths
基金 国家自然科学基金项目 (2 95 710 13 )
关键词 ⅢB族金属 表征 合成 苯乙酰缩氨基硫脲 配合物 抗肿瘤活性 结构 acetophenon thiosemicarbazone complex antitumor
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  • 1Dimmock J R,Smith L M J.Syntheses and evaluation of ketals and dithioletals of conjugatel ketones principally for antineoplastic activity[J].J Pharm Sci,1980,69:575.
  • 2唐慧安,王哲民,朱巧军,王流芳,高翔.主族元素Sn的含硫希夫碱配合物的合成、表征、抗肿瘤活性[J].兰州大学学报(自然科学版),2001,37(1):121-122. 被引量:7
  • 3Geary W J.The use of conductivity measurements in organic solvents for the characterization of coordination compound[J].Coord Chem Rev,1971,7:81.
  • 4Berns R.Preparation and oxygenation of some five-coordinate lewis base adducts of Iron bis(1.2-dithidenes)[J].Inorg Chem,1971,7(2):277.
  • 5Mital S P,Singh R V,Tandon J P.Synthesis and studies of somicarbazone to lan thanum(Ⅲ)and Sm coordination complexes[J].Synth React Inorg Met-org Chem,1982,12(23):169-286.
  • 6Melir G.Hand Book of Inorganic Chemistry (8th Edit)[M].Sust,1982.
  • 7Scholar R P,Merbach A E.EPR and other spectra of trigonal bipyramidal metal complexes[J].Inorg Chim Acta,1975,15:16.

二级参考文献2

  • 1Geary W J.The use of conductivity measurements in organic solvents for the characterization of coordination compounds[].Coordination Chemistry Reviews.1971
  • 2Burns R.Preparation and oxygenation of some five-coordinate lewis base adducts of Iron bis(1, 2-dithiodenes)[].Inorganic Chemistry.1971

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