摘要
本文论证了化学反应标准平衡常数Kφ的表达式及无量纲性,给出了各种情况下标准平衡常数Kφ和正逆向反应速度常数k f、k b之间的关联式.同时讨论了Kφ的热力学和统计力学的计算方法,对目前流行的K_p~φ和K_c~φ的关系进行了修正.
This Paper indicates the expression of the standard equilibrium constant K?? which is undi mensional in chemical reaction, The relationship between the standard equilibrium constant K~φ and rate constant k_f. k_h is given under various conditions. At the same time, we also discuss the computational method of K~φ, and remake the relationship between K_P~φ and K_c~φ.
出处
《淮北煤师院学报(自然科学版)》
1989年第1期67-74,共8页
Journal of Huaibei Teachers College(Natural Sciences Edition)