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黑果菝葜皂甙的化学结构和灭螺活性研究 被引量:1

Studies on the Structures and Molluscicidal Activity of Saponins from Smilax Glauco-China Warb
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摘要 百合科植物黑果拔葜根茎的甲醇提取物,经硅胶柱层析及制备性薄层层析,分离得到两种甾体皂甙成分——黑果拔葜皂甙 A 和黑果拔葜皂甙 B。通过乙酰化、酸水解、红外光谱、质谱和一些物理常数等的测定,推断黑果拔葜皂甙 A 的化学结构为知母皂甙元-3-0-[β-D-葡萄吡喃糖基(1→?)]-[-L-鼠李吡喃糖基(1→?)]-B-D-葡萄吡喃糖甙。灭螺活性试验表明黑果拔葜粗皂甙及纯品皂甙 A 均有明显的杀螺作用。 Two steroidal saponins named Heiguobaqia saponin A and Heiguobaqia saponin B were isolated from the methanol extract of rhizome of Smilax glauco-china Warb (Liliaceae) by chromatographic method.On the basis of acetylation acid hydrolysis、Infrared Spectrum、Mass Spectrum and some physical contants etc.The chemical structure of Saponin A has been elucidated and identified as sarsasapogenin-3-0[β-D-glucopyranosyl(1→?)] -[α-L-rhamnopyranosyl (1→?)]-β-D-glucopyranoside.Heiguobaqia Saponins weretestcd for molluscicidal activity.The crude,saponins ane Saponin A were shown to have strong killing activity.
机构地区 安徽大学生物系
出处 《安徽大学学报(自然科学版)》 CAS 1992年第4期92-96,62,共6页 Journal of Anhui University(Natural Science Edition)
基金 安徽省教委基金资助。
关键词 黑果拔葜 甾体皂甙 灭螺 皂角甙 Smilax glauco-china Warb Heiguo baqia saponin A steroidal saponin molluscicidal
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  • 1刘承来,陈延镛,葛绍彬,李伯刚.薯蓣属植物化学成分的研究——Ⅱ.叉蕊薯蓣中甾体皂甙的分离和鉴定[J]药学学报,1983(08).
  • 2江苏新医学院.中药大辞典[M]上海人民出版社,1977.

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