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多官能团手性氨基醇配体的合成 被引量：2

Synthesis of a novel polyfuntional chiral ligand
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摘要 以天然手性氨基酸为原料 ,合成了一个新的多官能团手性氨基醇配体 ,并用红外、核磁。 methyl-pyrrolidine-2-ylmethyl)-amino]-1,1,3-triphenyl-propan-1-ol (6) synthesized from natural amino acids is a new multifunctional chiral amino alcohol ligand. The structure of the substance was confirmed by IR, NMR, and elemental analysis.
作者 邱丽华 张雅文
机构地区 苏州大学化学化工系
出处 《苏州大学学报（自然科学版）》 CAS 2002年第4期76-79,共4页 Journal of Soochow University(Natural Science Edition)
关键词 多官能团手性氨基醇配体 合成 手性氨基酸 不对称催化剂 结构表征 还原反应 chiral amino alcohol chiral catalyst multifunctional chiral ligand
分类号 O623.734 [理学—有机化学]
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参考文献9

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同被引文献25

  • 1邱丽华,沈宗旋,葛健锋,张雅文.Synthesis of a Chiral Tridentate Ligand from Proline and Its Application to Enantioselective Addition of Diethylzinc to Aldehydes[J].Chinese Journal of Chemistry,2005,23(7):898-900. 被引量：1
  • 2卢翠芬,杨桂春,陈祖兴.L-酪氨酸合成手性噁唑烷酮的研究[J].湖北大学学报（自然科学版）,2005,27(4):366-368. 被引量：4
  • 3郝宝玉,俞迪虎,陈新志.L-2-氨基丙醇的合成新工艺[J].染料与染色,2005,42(6):35-36. 被引量：6
  • 4Corey E J, Bakshi R K, Shibata S. A Stable and Easily Prepared Catalyst for the Enantioselective Reduction of Ketones. Applications to Muhistep Syntheses. J Org Chem,1988,53:2861-2863
  • 5Noyori R, Suga S, Kitamura M. Enantioseleetive Addition of Diorganozincs to Aldehydes Catalyzed by β - Amino Alcohols. J Org Chem, 1990,382 : 19 - 37
  • 6Karrer P, Karrer W, Thomann H, et al. An Improved Procedure for Preparing Chiral Aminoalcohols. Chim Acta,2001,4:76
  • 7Karrer P, Portmann P, Suter M H. Synthesis and Crystal Structure of the Novel Chiral o - Hydroxyphenyloxazoline Metal Complexes. Chim Acta, 1999,32 : 1156-1158
  • 8Seki H, Kogn K, Matsuo H, et al. Studies on Optically Active Amino Acids. Synthesis of Optically Active Alpha - amino alcohols by the Reduction of Alpha - amino Acid Esters with Sodium Borohydride. Chem Pham Bull, 1995,13:995-998
  • 9Faita G, Paio A, Quadrelli P, et al. Solid Supported Chiral Auxiliaries in Asymmetric Synthesis. ( Part 2) : Catalysis of 1, 3 - Dipolar Cycloadditions by Mg(Ⅱ) Cation. Tetrahedron, 2001, 57: 8313-8322
  • 10Barta N S, SidlerD R, Somerville K B, et al. Practical Modifications and Applications of the Sharpless Asymmetric aminohydro - xylation in the One - pot Preparation of Chiral Oxazolidin - 2 - ones. Org Letters,2000,2:2821-2824

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苏州大学学报（自然科学版）
2002年 第4期

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