新型配体 9′-( 4 ,5-二烷基硫-1,3-二硫杂环戊烯-2-叉) 4′,5′-二氮杂芴的铜 (I)配合物的合成及光谱研究(英文)

Synthesis and spectral sdudies of copper (I) complexes with new type ligands,4′,5′-Diaza-9′-[4,5-bis(alkylthio)-1,3-dithiol-2-ylidene] fluorenes

首次用Cu(CH3CN) 4 ClO4与新型配体 9′ (4,5 二烷基硫 1,3 二硫杂环戊烯 2 叉 ) 4′ ,5′ 二氮杂芴合成了两种Cu(I)配合物 ,并对配合物进行了元素分析和光谱的测定 .

Two Cu(I) complexes were obtained by reacting [Cu(CH 3CN) 4]ClO 4 with new type of ligands,4′,5′-diaza-9′-[4,5-bis(alkylthio)-1,3-dithiol-2-ylidene] fluorenes. These complexes were measured by elemental analyses and spectra. One dimensional structure of these complexes was proposed.