期刊文献+

N_5分子及其HMO法研究 被引量:2

Study on N_5 Molecule and Its HMO Method
下载PDF
导出
摘要 初步介绍了新制备的N5分子的有关内容,并用HMO法对其离域大π键进行了研究,得出了几个很有意义的结论。 This paper made a brief introduction about the newly prepared N5 molecule. Through HMO method, its conjugated large π bond was studied. On the basis of the research, a few significant conclusions were drawn.
出处 《孝感师专学报》 1999年第4期45-48,共4页 Journal of Xiaogan University
关键词 N5分子 HMO法 离域Π键 氮与分子 无机化学 轨道能量 波函数 N_5 molecule HMO method conjugated π bond
  • 相关文献

同被引文献43

  • 1张光全,董海山.氮簇合物——潜在的高能密度材料候选物[J].含能材料,2004,12(A01):105-113. 被引量:12
  • 2张德雄,张衍,王伟平,薛金星.高能量密度材料(HEDM)研究开发现状及展望[J].固体火箭技术,2005,28(4):284-288. 被引量:21
  • 3Xu Wenguo, Li Guoliang, Wang Lijie, et al. Ab initio and density functional theory study of the mechanism of synthesis of the N; cation[J]. Chemical Physics Letters, 1999, 314(34): 300-306.
  • 4Robert P, Jana R, Karl J, et al. On the nature of bonding in N5^+ ion[J]. Journal of Molecular Structure (Theochem), 2001, 545(1/2/3): 255-264.
  • 5Ashwani V, William W W, Vandana V, et al. Polynitrogen chemistry: synthesis, characterization, and crystal structure of surprisingly stable fluoroantimonate salts of N5^+[J]. Journal of American Chemical Society, 2001, 123(26): 6 308-6 313.
  • 6William W W, Ashwani V, Vandana V, et al. Polynitrogen chemistry: preparation and characterization of (N5)2SnF6, NsSnF5, and N5B(CF3)4[J]. Chemistry-A European Journal, 2003, 9(12): 2 840- 2 844.
  • 7Heather M N, Mark S G, Karl C, et al. On the existence of FNs, a theoretical and experimental study[J]. Journal of the Physical Chemistry A, 2003, 107(34): 6 638-6 647.
  • 8Ralf H, Stefan S, Thorstern S, et al. High-energy-density materials: synthesis and characterization of N5^+[P(N3)6]^-, N5^+[B(N3)4]^-, N5^+[HF2]^-nHF, N5^+[BF4]^-, N5^+[PF6]^-, and N5^+[SO3F]^-[J]. Angew Chem Int Ed, 2004, 43(37): 4 919-4 924.
  • 9Dixon D A, Feller D, Christe K O, et al. Enthalpies of formation of gas phase N3, N3^-, N5^+, and N5^- from ab initio molecular orbital theory, stability predictions for N5^+N3^- and N5^+N5^-, and experimental evidence for the insability of N5^+N3^-[J]. Journal of American Chemical Society, 2004, 126(3): 834-843.
  • 10Gagliardi L, Orlandi G, Evangelisti S, et al. A theoretical study of the nitrogen clusters formed from the ions N3^-, N5^+, and N5^-[J]. Journal of Chemical Physics, 2001, 114(24): 10 733-10 737.

引证文献2

二级引证文献3

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部