摘要
Stabilization and volume reduction Of spent radioactive ion-exchange resins (IERs) were studied. Stabilization technology includes volume reduction with wet Chemical oxidation process and immobilization of the residue into cement. Under suitable conditions, the exhaussted radioactive ion-exchange resins were dissolved successfully in a H2,O2-Fe2+/Cu2+ catalytic oxidation system (Fenton reagent). The analytical results indicated that the radioactive nuclides loaded in the resins were concentrated in decomposed solution and solid residues. The process parameters of wet chemical oxidation and solidification were also obtained. The decomposition ratios were 100% and more than 90% for canon and anion IERs respectively. The waste volume was decreased by 40% compared with that of original spent resins.
Stabilization and volume reduction Of spent radioactive ion-exchange resins (IERs) were studied. Stabilization technology includes volume reduction with wet Chemical oxidation process and immobilization of the residue into cement. Under suitable conditions, the exhaussted radioactive ion-exchange resins were dissolved successfully in a H2,O2-Fe2+/Cu2+ catalytic oxidation system (Fenton reagent). The analytical results indicated that the radioactive nuclides loaded in the resins were concentrated in decomposed solution and solid residues. The process parameters of wet chemical oxidation and solidification were also obtained. The decomposition ratios were 100% and more than 90% for canon and anion IERs respectively. The waste volume was decreased by 40% compared with that of original spent resins.
