摘要
bState Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China cShanghai Hong Kong Joint Laboratory in Chemical Synthesis, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China New chiral N,S ligands with oxazoline and thiophenyl substituents at benzene ring and benzylic position have been prepared and applied in palladium catalyzed asymmetric allylic alkylation reaction to provide the product with high yield and entantioselectivity ( 82%-93% ee ).
bState Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China cShanghai Hong Kong Joint Laboratory in Chemical Synthesis, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China New chiral N,S ligands with oxazoline and thiophenyl substituents at benzene ring and benzylic position have been prepared and applied in palladium catalyzed asymmetric allylic alkylation reaction to provide the product with high yield and entantioselectivity ( 82%-93% ee ).
基金
theNationalNaturalScienceFoundationofChina (No .2 0 132 0 10 )
theMajorStateBasicResearchDevelopmentProgram (No.G2 0 0 0 0 775 0 6 )
theNationalOutstandingYouthFund ChineseAcademyofSciences
theShanghaiCommitteeofSci enceandTechnology
