Synthesis and Structure of a New Dinuclear Molybdenum (I) Compound with Cyclohexanthiolate Ligand, [Mo_2(SC_6H_(11))_2(CO)_8]
Synthesis and Structure of a New Dinuclear Molybdenum(Ⅰ)Compound with Cyclohexanthiolate Ligand,[Mo_2(SC_6H_(11)_2(CO)_8]
摘要
Molybdenum(I) -compound [Mo2(SC6H11)2(CO)8]1,crystallizes in monoclinic,space group P21/c with a=9.5863(9),b=9.4469(9),c=13.869(1)A,β=99.697(2)°,V=1238.1(2)A^3,Z=2,Dc=1.734g/cm^3 ,μ=12.23cm^-1 and F(000)=644.The final R=0.0455 and wR=0.1159 for 1590 observed reflections with I>2ó(I).1 possesses a rhombic bimetallic core MoS2Mo with the Mo-Mo bond length of 2.975(1) and Mo-S of 2.485(2)A。
基金
This research was supported by grants from the NNSFC
SKLSC(No.01008 and No.980148-2)
参考文献12
-
1Lu, S.; Okura, N.; Yoshida, T.; Otsuka, S.; Nitrotsu, K.; Higuchi, T. J. Am. Chem. Soc. 1983, 105, 7470-7473.
-
2Bose, K. S.; Lamberty, P. E.; Kovaes, J. E.; Sinn, E.; Averil, B. A. Polyhedron 1986, 5, 393-398.
-
3Eldredge, P. A.; Bryan, R. F.; Sinn, E.; Averill, B. A. J. Am. Chem. Soc. 1988, 110, 5573-5575.
-
4Zhuang, B.; McDonald, J. W.; Schultz, F. A.; Newton, W. E. Organometallics 1984, 3, 943-945.
-
5Zhuang, B. T.; Huang, L.; He, L. Chinese J. Struct. Chem. 1995, 14, 359-363.
-
6Zhuang, B.; Huang, L.; He, L.; Yang, Y.; Lu, J. Inorg. Chim. Acta 1987, 127, L7-8.
-
7Zhuang, B.; Huang, L.; He, L.; Yang, Y.; Lu, J. Huaxue Xuebao 1989, 47, 25-30.
-
8Zhuang, B.; Huang, L.; He, L.; Yang, Y.; Lu, J. Inorg. Chim. Acta 1986, 116, L4-43.
-
9Zhuang, B.; Huang, L.; He, L.; Yang, Y.; Lu, J. Inorg. Chim. Acta 1989, 157, 85-90.
-
10Wei, Q.; Zhuang, B.; Chen, J. Acta Cryst. 1999, C55, 2047-2049.
-
1陈寿山,王家喜,王序昆,王宏根.双(η~5-异丙基环戊二烯基)六羰基二钼的合成及分子结构[J].Chinese Journal of Structural Chemistry,1993,12(3):229-232. 被引量：3
-
2郑碧仙,黄锦顺,卢嘉锡.含氧桥的笼状化合物[Mo_5P_2O_(23)]^(6-)[(CH_3)_2NH_2]_5^(5+)-[H_3O]^+·1/2(CH_3)_2NCHo·1/2H_2O的合成和结构[J].Chinese Journal of Structural Chemistry,1993,12(3):175-179.
-
3张钟宪,鲁晓明,刘顺诚.H_2Mo_8O_(26)[(n-Bu)_4N]_2[(CH_3)_2COHCH_2COCH_3]_2的合成与晶体结构[J].化学通报,2000,63(3):37-38. 被引量：2
-
4乔赤兵,孔繁荣.1,3,5-三甲苯三羰基钼热分解过程的研究[J].北京师范学院学报（自然科学版）,1992,13(4):56-59.
