摘要
综述了不同自愈体系的自愈机制,根据是否需要外加修复剂,将自愈体系分为本征型和外援型两类,其中本征型自愈体系的愈合机制是指非共价键(氢键作用、疏水作用、静电作用)和共价键(DA键、双硫键)的重新结合作用;外援型自愈体系是引入修复剂,利用修复剂修复损伤。最后,对自愈体系的主要的应用技术:层层自组装技术、微胶囊封装技术和化学转化膜技术进行了综述。
The re-healing mechanism of different re-healing coating systems is reviewed. According to whether a restorative agent is added or not, the re-healing coating systems may be divided into extrinsic re-healing coating system and intrinsic one. The intrinsic re-healing coating system mainly refers to the rebinding effect of non-covalent bonding, such as hydrogen bonding, hydrophobic effect and electrostatic interactions and covalent bonding, such as DA bonding and disulfide bonding. The extrinsic re-healing coating system relies on the incorporation of restorative agents, with the function of which the damage of a coating system may be restored. The main application technologies of re-healing coating system, such as layer-by-layer(LbL) self-assembly technology, microcapsule packaging technology and chemical conversion coating technology, are reviewed.
作者
张硕
许萍
张雅君
汪长征
韩芳
ZHANG Shuo;XU Ping;ZHANG Yajun;WANG Changzheng;HAN Fang(National Demonstration Center for Experimental Water Environment Education,Key Laboratory of Urban Stormwater System and Water Environment,Ministry of Education,Beijing University of Civil Engineering and Architecture,Beijing 100044,China)
出处
《腐蚀科学与防护技术》
CAS
CSCD
北大核心
2019年第1期92-100,共9页
Corrosion Science and Protection Technology
基金
国家自然科学基金(51578035)
北京建筑大学研究生创新项目(PG2018043)
北京建筑大学基金项目(00331615008)
北京市属高校基本科研业务费专项资金
城市雨水系统和水环境省部共建教育部重点实验室项目(PXM2014014210000057)~~
关键词
本征型自愈体系
外援型自愈体系
层层自组装
微胶囊封装
化学转化膜
intrinsic re-healing
extrinsic re-healing
layer-by-layer self-assembly
microcapsule packaging
chemical conversion coating
