摘要
A new complex [Ni（en）3]4[HVⅣ12VⅤ6O42（PO4）] has been hydrothermally synthesize d and characterized by X-Ray diffraction,IR and Elemental analysis.Single crystal X-ray analysis indicates that this compoud cry stallizes in cubic system,space group Im3m with a=17.4081（2）*!,V=5275.38（10）*! 3 ,R=0.0420,w R=0.1055,Z =2,D c =1.663g·cm -3 ,μ=2.297mm -1 ,F（000）=2636.The crystal structure consis ts of[Ni （en） 3 ] 2+ cations and{HV 18 O 42 （PO 4 ）} 8- cluster anion which construct from 18{VO 5 }.square pyramids.The VO 5 pyramids joined each other to form a {V 18 O 42 }cage hosting a tetrahedral{PO 4 } 3- moiety with disordered oxygen atoms .CCDC:185574.
A new complex [Ni(en)_3]_4[HV^(Ⅳ)_(12)V~Ⅴ_6O_(42)(PO_4)] has been hydrothermally synthesize d and characterized by X-Ray diffraction,IR and Elemental analysis.Single crystal X-ray analysis indicates that this compoud cry stallizes in cubic system,space group Im3m with a=17.4081(2)*!,V=5275.38(10)*! 3 ,R=0.0420,w R=0.1055,Z =2,D c =1.663g·cm -3 ,μ=2.297mm -1 ,F(000)=2636.The crystal structure consis ts of[Ni (en) 3 ] 2+ cations and{HV 18 O 42 (PO 4 )} 8- cluster anion which construct from 18{VO 5 }.square pyramids.The VO 5 pyramids joined each other to form a {V 18 O 42 }cage hosting a tetrahedral{PO 4 } 3- moiety with disordered oxygen atoms .CCDC:185574.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2002年第12期1233-1236,共4页
Chinese Journal of Inorganic Chemistry
基金
国家自然科学基金资助项目(No.20171045)
国家财政部和中科院"引进国外杰出人才"专项基金资助项目
福建省自然科学基金资助项目(No.E0210029)。
