5,10,15,20-四苯基卟啉锌与甲醇加合物谱学及结构研究

Spectroscopic and Structural Study on Interaction of(5,10,15,20- Tetraphenylporphyrinato) Zinc(Ⅱ) with Methanol

在氯仿溶液中利用紫外 -可见光谱及核磁共振研究了 5 ,10 ,15 ,2 0 -四苯基卟啉锌 (TPPZn)与甲醇(Me OH)的相互作用 ,发现 Me OH可与 TPPZn发生加合反应。单晶衍射分析表明加合物中 Me

Interaction of (5,10,15,20 tetraphenylporphyrinato)zinc(Ⅱ) (TPPZn) with methanol (MeOH) in chloroform at room temperature was investigated by UV Visible spectrometry and 1H NMR.The results of X ray single crystal study show that methanol coordinates to TPPZn and forms five coordinated compound.