6,6′-二硝基四氧化呋咱并[b,d,b′,d′]联苯的合成

SYNTHESIS OF 6,6'-DINITRO TETRAFUROXANO[b,d,b',d'] BIPHENYL

运用往芳环上引入氧化呋咱基团的方法合成了无氢化合物6,6′-二硝基四氧化呋咱并[b,d,b′,d′]联苯(3),并对其部分性质做了报道。3,5,3′,5′-四叠氮基-2,4,6,2′,4′-五硝基联苯(1)经硝化后生成3,5,3′,5′-四叠氮基-2,4,6,2′,4′,6′-六硝基联苯(2),将(2)热解脱氮就得到题称化合物(3)。

A hydrogen-free compound 6,6'-dinitro tetrafuroxano (b, d, b' , d') biphenyl (3) was synthesized through the introduction of furoxano groups on the aromatic ring and some of its properties are reported. 3, 5, 3', 5'- tetraazido- 2, 4, 6, 2', 4', 5'- hexanitro biphenyl ( 2 ) was prepared through nitrating 3, 5, 3', 5'- tetraazido- 2, 4,6, 2', 4'-pentanitrobiphenyl, and then pyrolyzed to the title compound (3).