Applicability of mass action law to sulphur distribution between slag melts and liquid iron 被引量：8

Applicability of mass action law to sulphur distribution between slag melts and liquid iron

下载PDF

导出

摘要 According to the mass action law and the coexistence theory of slagstructure, the calculating models of mass action concentration for CaO-MgO-FeO-Fe_2O_3-SiO_2,CaO-MgO-MnO-FeO-Fe_2O_3-P_2O_5-SiO_2 and CaO-MgO-MnO-FeO-Fe_2O_3-Al_2O_3-P_2O_5-SiO_2 slag melts areformulated and sulphur distribution between the slag melts and liquid iron is treated. It is foundthat CaO, MnO and FeO promote desulphurization, while MgO is detrimental to desulphurization. Inaddition, the sulphur distribution coefficients between the slag melts and liquid iron andpresented. According to the mass action law and the coexistence theory of slagstructure, the calculating models of mass action concentration for CaO-MgO-FeO-Fe_2O_3-SiO_2,CaO-MgO-MnO-FeO-Fe_2O_3-P_2O_5-SiO_2 and CaO-MgO-MnO-FeO-Fe_2O_3-Al_2O_3-P_2O_5-SiO_2 slag melts areformulated and sulphur distribution between the slag melts and liquid iron is treated. It is foundthat CaO, MnO and FeO promote desulphurization, while MgO is detrimental to desulphurization. Inaddition, the sulphur distribution coefficients between the slag melts and liquid iron andpresented.

作者 Jian Zhang Metallurgy School, University of Science and Technology Beijing, Beijing 100083, China

出处《Journal of University of Science and Technology Beijing》 CSCD 2002年第2期90-98,共9页 北京科技大学学报（英文版）

关键词 mass action law coexistence theory of slag structure activity massaction concentration mass action law coexistence theory of slag structure activity massaction concentration

分类号 TF534 [冶金工程—钢铁冶金]

引文网络
相关文献

参考文献1

1B. K. D. P. Rao,D D. R. Gaskell.The thermodynamic properties of melts in the system MnO-SiO2[J].Metallurgical Transactions B.1981(2)

同被引文献21

1谢洪恩.Ti(C,N)对高钛型高炉渣脱硫能力的影响[J].中国冶金,2020,30(1):32-37. 被引量：6
2齐涛,王伟菁,魏广叶,朱兆武,曲景奎,王丽娜,张绘.战略性稀有金属资源绿色高值利用技术进展[J].过程工程学报,2019,19(S01):10-24. 被引量：12
3J. Zhang (Metallurgical Engineering School, University of Science and Technology Beijing, Beijing 100083, China).THE APPLICATION OF THE LAW OF MASS ACTION IN COMBINATION WITH THE COEXISTENCE THEORY OF SLAG STRUCTURE TO THE MULTICOMPONENT SLAG SYSTEMS[J].Acta Metallurgica Sinica(English Letters),2001,14(3):177-190. 被引量：14
4王新国,丁伟中,唐恺,蒋国昌,徐匡迪.Experimental thermodynamic research on equilibrium between silicon alloy and SiO_2-CaO-Al_2O_3 melt[J].中国有色金属学会会刊：英文版,2001,11(4):535-539. 被引量：2
5ZHANGJian.Application of annexation principle to the study of thermodynamic properties of ternary molten salts CaCl_2-MgC_2-NaCl[J].Rare Metals,2004,23(3):209-213. 被引量：8
6何环宇,王庆祥,曾小宁.MgO含量对高炉炉渣粘度的影响[J].钢铁研究学报,2006,18(6):11-13. 被引量：57
7郭汉杰,赵伟洁,李林,杨学民.基于共存理论的二元系强电解质水溶液质量作用浓度通用热力学模型[J].过程工程学报,2007,7(2):347-353. 被引量：10
8Hanjie Guo,Weijie Zhao,Xuemin Yang.Calculating models of mass action concentrations for NaBr(aq), LiNO_3(aq), HNO_3(aq), and KF(aq) binary solutions[J].Journal of University of Science and Technology Beijing,2007,14(3):204-211. 被引量：8
9吕庆,李福民,顾林娜,侯大华.含碱高炉渣排碱、脱硫能力的实验研究[J].东北大学学报（自然科学版）,2007,28(11):1590-1593. 被引量：21
10张振峰,吕庆,高峰,李福民,张淑会.高TiO2、Al2O3炉渣脱硫能力的试验研究[J].钢铁,2008,43(2):14-17. 被引量：12

引证文献8

1史成斌,郭汉杰,丁汝才,焦晋沙,杨学民.CaO-SiO_2-MgO-Al_2O_3渣系与碳饱和铁液间硫分配比的热力学模型[J].过程工程学报,2010,10(S1):158-164. 被引量：9
2Hai-yan Tang Jing-she Li.Thermodynamic analysis on the formation mechanism of MgO·Al_2O_3 spinel type inclusions in casing steel[J].International Journal of Minerals,Metallurgy and Materials,2010,17(1):32-38. 被引量：1
3张盟,郭汉杰,丁汝才,王效东,史成斌,杨学民.CaO-SiO_2-MgO-Al_2O_3炼铁渣系硫化物容量的热力学模型[J].北京科技大学学报,2011,33(9):1079-1084. 被引量：4
4王飞,郭汉杰,杨学民.基于最小Gibbs自由能原理的CaO-SiO_2炉渣和Si-Ca金属两相体系平衡热力学模型[J].中国有色金属学报,2012,22(6):1785-1790. 被引量：4
5李鹏程,杨学民,张鉴.CaO-MgO-FeO-Fe_2O_3-SiO_2炼钢渣系磷分配比的热力学模型[J].北京科技大学学报,2014,36(12):1608-1614. 被引量：4
6袁骧,张建良,毛瑞,刘征建.镁铝比对高炉渣脱硫能力的影响[J].东北大学学报（自然科学版）,2015,36(11):1609-1613. 被引量：19
7张贺顺,许仁泽,张建良,王志宇,刘长江.首钢京唐高炉渣脱硫性能研究[J].钢铁研究,2016,44(5):14-18. 被引量：6
8尹学杰,陈德胜,王丽娜,赵宏欣,甄玉兰,齐涛,王猛.Na_(2)O-TiO_(2)-SiO_(2)-CaO-Al_(2)O_(3)-V2O5-MnO-MgO-FeO渣系渣铁间硫分配比热力学模型[J].过程工程学报,2023,23(1):124-135.

二级引证文献41

1王志宇,沙华玮,张永新.湛江钢铁低镁铝比高炉渣生产实践[J].冶金管理,2020,0(3):9-9.
2李霞,丁跃华,黄帮福.高炉CaO-SiO_2-Al_2O_3-MgO-TiO_2渣与铁液间硫分配比的热力学模型[J].钢铁研究学报,2012,24(7):19-23. 被引量：7
3孙昊延,曹立军,薛庆国,王静松.Zr基块体非晶合金的非真空制备及其非等温晶化行为[J].稀有金属材料与工程,2012,41(10):1814-1818. 被引量：1
4吴铖川,成国光,龙鹄.含Ce_2O_3渣系作用浓度的计算模型[J].中国有色金属学报,2013,23(10):2999-3005. 被引量：5
5李林,李永麒,郭汉杰.钛磁铁矿球团预还原影响因素的实验研究[J].矿冶工程,2014,34(3):80-84. 被引量：5
6李林,郭汉杰,孟祥龙,王代军,李永麒.钛磁铁矿球团预还原与熔分关系试验研究[J].矿冶工程,2015,35(3):106-110. 被引量：5
7兰臣臣,张淑会,曹丽华,吕庆,孙艳芹.低钛高炉渣流动性和脱硫能力的试验研究[J].上海金属,2015,37(5):42-46. 被引量：1
8张明博,仇圣桃,朱荣,韩宇.转炉CaO渣系加锂云母矿冶炼超低磷钢的热力学分析和工业试验[J].特殊钢,2016,37(3):13-19. 被引量：1
9李明周,童长仁,汪金良,黄金堤,李俊标.基于Rand-MQC耦合算法的高强度铜闪速熔炼多相平衡热力学分析[J].有色金属（冶炼部分）,2017(2):4-9. 被引量：2
10董晓旭,张淑会,兰臣臣,吕庆.低钛高炉渣脱硫能力研究[J].矿冶工程,2017,37(2):88-90. 被引量：3

1陈枫.真空下表面运动对合金元素从液态铁中蒸发速度的影响[J].真空冶金,1989(1):1-33.
2Jian Zhang(Metallurgy School, University of Science and Technology Beijing, Beijing 100083, China).Calculating Models of Mass Action Concentrations for Fe-P and Cr-P Melts and Optimization of Their Thermodynamic Parameters[J].International Journal of Minerals,Metallurgy and Materials,1999,13(3):174-177. 被引量：2
3金泽洪.稀土加入工艺对钢中稀土及硫分布的影响[J].特殊钢,1999,20(2):40-42. 被引量：9
4ZHANG Jian.Coexistence Theory of Slag Structure and Its Application to Calculation of Oxidizing Capability of Slag Melts[J].Journal of Iron and Steel Research(International),2003,10(1):1-10. 被引量：29
5张鉴.Applicability of law of mass action to distribution of manganese between slag melts and liquid iron[J].中国有色金属学会会刊：英文版,2001,11(5):778-783. 被引量：1
6张鉴.Mg-Al,Sr-Al和Ba-Al熔体的作用浓度计算模型和热力学参数确定[J].包头钢铁学院学报,2001,20(3):214-218. 被引量：1
7Jian Zhang,Rong Zhu Metallurgy School, University of Science and Technology Beijing, Beijing 100083, China.Thermodynamic Properties of Mn-P and Fe-Mn-P Melts[J].International Journal of Minerals,Metallurgy and Materials,2000,14(1):10-13. 被引量：3
8张士岩,卢永,王书桓.液态铁基合金中氮溶解度的影响因素[J].钢铁研究,2006,34(1):1-3. 被引量：2
9Tong-sheng ZHANG,De-yong WANG,Mao-fa JIANG.Effect of Magnesium on Evolution of Oxide and Sulphide in Liquid Iron at 1873K[J].Journal of Iron and Steel Research(International),2014,21(12):1073-1080. 被引量：11
10牛求彬,刘纯厚,曹洪文.中磷生铁用CaO-Fe_2O_3-Al_2O_3系和CaO-Fe_2O_3系熔剂炉外脱磷的研究[J].化工冶金,1991,12(4):290-294.

Journal of University of Science and Technology Beijing

2002年第2期

浏览历史

内容加载中请稍等...

Applicability of mass action law to sulphur distribution between slag melts and liquid iron 被引量：8

参考文献1

同被引文献21

引证文献8

二级引证文献41

相关作者

相关机构

相关主题

浏览历史