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Double[3+2] cycloaddition of nitrile oxides with allenoates:Synthesis of spirobidihydroisoxazoles

Double[3+2] cycloaddition of nitrile oxides with allenoates:Synthesis of spirobidihydroisoxazoles
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摘要 The double [3 + 2] cycloaddition of allenoates with nitrile oxides is presented. The reaction worked well under mild reaction conditions to give the spirobidihydroisoxazole in moderate to excellent yields with excellent diastereoselectivities. The two dihydroisoxazole rings have been formed via a sequential double [3 + 2] cycloaddition. The double [3 + 2] cycloaddition of allenoates with nitrile oxides is presented. The reaction worked well under mild reaction conditions to give the spirobidihydroisoxazole in moderate to excellent yields with excellent diastereoselectivities. The two dihydroisoxazole rings have been formed via a sequential double [3 + 2] cycloaddition.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2019年第2期363-366,共4页 中国化学快报(英文版)
基金 supported by the National Natural Science Foundation of China(Nos. 21372256, 21572264)
关键词 CYCLOADDITION ALLENOATE NITRILE OXIDE SPIROCYCLIC heterocyle Cycloaddition Allenoate Nitrile oxide Spirocyclic heterocyle
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