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Glassy dynamics of water at interface with biomolecules: A Mode Coupling Theory test 被引量:1

Glassy dynamics of water at interface with biomolecules: A Mode Coupling Theory test
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摘要 We study the slow dynamics of hydration water upon cooling in two different biological aqueous solutions,one containing a molecule of lysozyme and another with trehalose molecules.In particular we test if the glassy behaviour of these solutions fulfils the predictions of the popular Mode Coupling Theory of glassy dynamics.In particular we test the Time Temperature Superposition Principle and the matching of the exponents of the theory.Our results confirm that this theory is able to describe the dynamical behaviour of supercooled water also in non ideal cases as the ones under investigation in the region of mild supercooling. We study the slow dynamics of hydration water upon cooling in two different biological aqueous solutions, one containing a molecule of lysozyme and another with trehalose molecules. In particular we test if the glassy behaviour of these solutions fulfils the predictions of the popular Mode Coupling Theory of glassy dynamics. In particular we test the Time Temperature Superposition Principle and the matching of the exponents of the theory. Our results confirm that this theory is able to describe the dynamical behaviour of supercooled water also in non ideal cases as the ones under investigation in the region of mild supercooling.
出处 《Science China(Physics,Mechanics & Astronomy)》 SCIE EI CAS CSCD 2019年第10期82-86,共5页 中国科学:物理学、力学、天文学(英文版)
关键词 GLASSY DYNAMICS AQUEOUS SOLUTIONS biomolecules MOLECULAR DYNAMICS glassy dynamics aqueous solutions biomolecules Molecular Dynamics
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