摘要
Owing to their inexpensive and environmentally friendly properties,iron-based catalysts have been actively investigated for new organic reactions.In this account,we summarized our recent results on iron-catalyzed cross-coupling reactions and homo-coupling reactions.With iron-based catalysts,we constructed diverse carbon-carbon bonds,i.e.,C(sp^2)-C(sp^3),C(sp^3)-C(sp^3),C(sp^3)-C(sp^2)and C(sp^2)-C(sp^2)bonds.In order to demonstrate the usefulness of our iron protocol,we also carried out these reactions on gram-scale reactions,leading to good yields.
Owing to their inexpensive and environmentally friendly properties, iron-based catalysts have been actively investigated for new organic reactions. In this account, we summarized our recent results on iron-catalyzed cross-coupling reactions and homo-coupling reactions. With iron-based catalysts, we constructed diverse carbon-carbon bonds, i.e., C(sp^2)-C(sp^3), C(sp^3)-C(sp^3), C(sp^3)-C(sp^2) and C(sp^2)-C(sp^2) bonds. In order to demonstrate the usefulness of our iron protocol, we also carried out these reactions on gram-scale reactions, leading to good yields
基金
financed by National Natural Science Foundation of China (Nos. 21672181, 21272199)
GRF/RGC (Nos. 403012, CUHK14309216, CUHK14303815)
grant to the State Key Laboratory of Synthetic Chemistry from the Innovation and Technology Commission, The Chinese Academy of Sciences-Croucher Foundation Funding Scheme for Joint Laboratories
Direct Grant (No. 4053325) from The Chinese University of Hong Kong
