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Recent progress on pure organic room temperature phosphorescence materials based on host-guest interactions 被引量:4

Recent progress on pure organic room temperature phosphorescence materials based on host-guest interactions
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摘要 Pure organic room temperature phosphorescence(RTP) has been attracting a lot interest recently. So far,many strategies have succeeded in achieving efficient organic RTP materials by increasing the rate of intersystem crossing(ISC) and suppressing non-radiative transitions. In supramolecular chemistry, the control and regulation of molecular recognition based on the role of the host and guest in supramolecular polymers matrix, has attracted much attention. Recently, researchers have successfully achieved room temperature phosphorescence of pure organic complexes through host-guest interactions. The host molecule specifically includes the phosphorescent guest to reduce non-radiative transitions and enhance room temperature phosphorescence emission. This review aims to describe the developments and achievements of pure organic room temperature phosphorescence systems through the mechanism of host-guest interactions in recent years, and demonstrates the exploration and pursuit of phosphorescent materials of researchers in different fields. Pure organic room temperature phosphorescence(RTP) has been attracting a lot interest recently. So far,many strategies have succeeded in achieving efficient organic RTP materials by increasing the rate of intersystem crossing(ISC) and suppressing non-radiative transitions. In supramolecular chemistry, the control and regulation of molecular recognition based on the role of the host and guest in supramolecular polymers matrix, has attracted much attention. Recently, researchers have successfully achieved room temperature phosphorescence of pure organic complexes through host-guest interactions. The host molecule specifically includes the phosphorescent guest to reduce non-radiative transitions and enhance room temperature phosphorescence emission. This review aims to describe the developments and achievements of pure organic room temperature phosphorescence systems through the mechanism of host-guest interactions in recent years, and demonstrates the exploration and pursuit of phosphorescent materials of researchers in different fields.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2019年第10期1809-1814,共6页 中国化学快报(英文版)
基金 financial support from the National Natural Science Foundation of China (NSFC) (Nos. 21788102, 21722603 and 21871083) Project supported by Shanghai Municipal Science and Technology Major Project (No. 2018SHZDZX03) the Innovation Program of Shanghai Municipal Education Commission (No. 2017-01-07-00-02-E00010) State Key Laboratory for Modification of Chemical Fibers and Polymer Materials (No. KF1803) Donghua University and the Fundamental Research Funds (No. KF1803) for the Central Universities
关键词 PURE ORGANIC room temperature phosphorescence HOST-GUEST interactions SUPRAMOLECULE MACROCYCLIC structure Film MATRIX Crystal MATRIX Pure organic room temperature phosphorescence Host-guest interactions Supramolecule Macrocyclic structure Film matrix Crystal matrix
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