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Asymmetric Difluoromethylthiolation of Carbon Nucleophiles with Optically Pure Difluoromethylthiolating Reagents Derived from Camphorsultam 被引量:2

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摘要 The invention of a family of optically pure electrophilic difluoromethylthiolating reagents 9a-c based on the camphorsultam skeleton was described.These reagents reacted with a variety of soft carbon nucleophiles such as oxazolone,oxindole,benzolactone and β-ketoester in good to excellent enantioselectivities.
出处 《Chinese Journal of Chemistry》 SCIE CAS CSCD 2019年第10期1041-1050,共10页 中国化学(英文版)
基金 The authors gratefully acknowledge the financial support from the National Natural Science Foundation of China(Nos.21625206,21632009,21421002,21572258)。
关键词 THIOL SKELETON REAGENT
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