摘要
利用端烯与巯基之间的光点击亲电加成化学反应,将表面富含巯基的二氧化硅微球均匀的附着在端烯修饰的聚二甲基硅氧烷(PDMS)表面,完成微球在PDMS表面的组装。分别采用傅里叶红外光谱仪、光学显微镜、接触角测量仪对修饰前后的基质材料进行表征检测,结果证实修饰在PDMS表面的端烯消失形成硫醚键,得到附着均匀的二氧化硅微球基质材料。通过这种方法,可以方便的在不同基材上负载二氧化硅微球。
By use of"light click chemistry"between of vinyl and thiol,Silica microspheres rich in sulfhydryl groups were evenly attached to the surface of polydimethylsiloxane(PDMS)modified by vinyl.Fourier transform infrared spectroscopy,optical microscopy and contact angle measurement were used to characterize the matrix materials before and after modification.The results showed that the vinyl modified on the surface of PDMS disappeared to form thioether bond,and the silica microsphere matrix materials with uniform adhesion were obtained.By this method,silica microspheres could be easily loaded on different substrates.
作者
沈启慧
单驿轩
徐欣辰
吕洋
刘岩
于东冬
周建光
SHEN Qi-hui;SHAN Yi-xuan;XU Xin-chen;LU Yang;LIU Yan;YU Dong-dong;ZHOU Jian-guang(Department of Chemistry and Pharmaceutical Engineering,Jilin Institute of Chemical Technology,Jilin 132022,China;Hospital of Zhejiang University,Hangzhou 310027,China;State Key Laboratory of Industrial Control Technology,College of Control Science and Engineering,Zhejiang University,Hangzhou 310058,China)
出处
《化学研究与应用》
CAS
CSCD
北大核心
2019年第11期2017-2020,共4页
Chemical Research and Application
基金
国家自然科学基金项目(21805107)
国家重点研发计划项目(2016YFC0800901-Z01)资助
