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X射线荧光光谱结合多元统计分析塑料打包带(绳) 被引量:19

Examination of Plastic Pack Belts(Ropes) via X-Ray Fluorescence Spectrometry Combined with Multivariate Statistical Analysis
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摘要 采用X射线荧光光谱法对32个塑料打包带(绳)样本进行检验,在80s的采集时间下,所得元素种类含量最为稳定。结合多元统计方法构建函数模型,将离差平方和法作为聚类方法,进行系统聚类时将平方欧氏距离作为测量区间以描述样本间的亲疏程度,将32个塑料打包带(绳)样本分为4类。通过样本之间的相关性和判别分析检验系统聚类的正确性和可靠性,挖掘出样本元素含量之间的内在联系。通过系统聚类的方法将32个塑料打包带(绳)样本进行分类,促进了模式识别技术在理化检验中的应用。 Herein,32 plastic pack belt(rope)samples were examined via X-ray fluorescence spectrometry.At the acquisition time of 80 s,the elemental composition was most stable.The function model was constructed by combining the multivariate statistical method.The ward’s method was selected as the clustering method.The square Euclidean distance was used as the measurement interval to describe the degree of affinity between the samples for hierarchical clustering.The 32 plastic pack belt(rope)samples were divided into four categories.The accuracy and reliability of the hierarchical clustering were tested via correlation between the samples and discriminant analysis,and the internal relationship between the contents of the sample elements was determined.In this experiment,32 samples of plastic pack belts(ropes)were classified using the hierarchical clustering method,which promoted the application of pattern recognition technology for physical and chemical examination.
作者 马枭 姜红 杨佳琦 Ma Xiao;Jiang Hong;Yang Jiaqi(School of Forensic Science,People1 s Public Security University of China,Beijing 100038,China;Key Laboratory of Evidence Science(China University of Political Science and Law),Ministry of Education,Beijing 100088,China)
出处 《激光与光电子学进展》 CSCD 北大核心 2019年第22期235-239,共5页 Laser & Optoelectronics Progress
基金 证据科学教育部重点实验室(中国政法大学)开放基金资助课题(2018KFKT08)
关键词 光谱学 X射线荧光光谱法 系统聚类 判别分析 塑料打包带(绳) spectroscopy X-ray fluorescence spectrometry hierarchical clustering method discriminant analysis plastic pack belts(ropes)
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