新型配合物[Zn（BIX）（NIPH）]n·1.5nH2O的合成及晶体结构

Synthesis, Structural Characterization and Properties of the compound [Zn（BIX）（NIPH）]n·1.5nH2O

本文利用常规方法合成了[Zn(BIX)(NIPH)]n·1.5nH2O,(BIX为1,4-(二亚甲基苯)二咪唑,H 2NIPH为5-硝基间苯二甲酸),并通过X-射线单晶衍射仪,元素分析对其进行结构表征。该化合物属于三斜晶系,空间群为P-1,a=10.151(3),A,b=11.014(3),A,c=11.774(3),A,α=67.057(4)°,β=74.024(3)°,γ=82.998(4)°。V=1165.2(5)3,C22H20N5O8 Zn,Mr=547.80。Dc=1.561 g/cm^3,F(000)=562,Z=2.R1=0.0481,wR2=0.1180。

An interest compound[Zn(BIX)(NIPH)]n·1.5nH 2O(BIX=1-(4-((1H-imidazol-1-yl)methyl)benzyl)-1H-imidazole),H 2NIPH=5-nitroisophthalic acid)is synthesized by conventional method and structurally characterized by single-crystal X-ray diffraction and elemental analysis.Compound crystallizes in the triclinic system,space group P-1,with a=10.151(3),b=11.014(3),A,c=11.774(3),A,α=67.057(4)°,A,β=74.024(3)°,γ=82.998(4)°.V=1165.2(5)3,C22H20N5O8 Zn,Mr=547.80.Dc=1.561 g/cm^3,F(000)=562,Z=2.R 1=0.0481,wR2=0.1180.