摘要
以氯化铜和氢氧化钠为原料,聚乙二醇为表面活性剂,水合肼为还原剂,水为溶剂,采用简单还原法制备氧化亚铜纳米线。然后通过水热法将纳米氧化亚铜、氧化锌和硫化镉进行复合。利用SEM和XRD对制备的产品进行表征。对制备的产品进行光催化活性测试。结果表明,在以汞灯为光源,亚甲基蓝的浓度为15 mg/L时,三元复合的产品活性最高,单纯氧化亚铜纳米线活性最低。
Copper oxide nanowires were prepared by simple reduction method using copper chloride and sodium hydroxide as raw materials,polyethylene glycol as surfactant,hydrazine hydrate as reducing agent and water as solvent.Then nano-cuprous oxide,zinc oxide and cadmium sulfide were compounded by hydrothermal method.The product was characterized by SEM and XRD.The photocatalytic activity of the prepared product was tested.The results show that when the mercury lamp is used as light source and the concentration of methylene blue is 15 mg/L,the activity of the ternary composite is the highest and the activity of pure cuprous oxide nanowires is the lowest.
作者
郭小峰
郝晨伟
王丽影
王宏波
柴坝
向前
罗义勇
GUO Xiao-feng;HAO Chen-wei;WANG Li-ying;WANG Hong-bo;CHAI Ba;XIANG Qian;LUO Yi-yong(State Key Laboratory Breeding Base of Mountain Bridge and Tunnel Engineering,Chongqing Jiaotong University,Chongqing 400074,China;School of Materials Science and Engineering,Chongqing Jiaotong University,Chongqing 400074,China;National Engineering Research Center for Inland Waterway Regulation,Chongqing Jiaotong University,Chongqing 400074,China;School of River&Ocean Engineering,Chongqing Jiaotong University,Chongqing 400074,China;National and Local Joint Engineering Laboratory of Traffic Civil Engineering Materials,Chongqing Jiaotong University,Chongqing 400074,China)
出处
《应用化工》
CAS
CSCD
北大核心
2019年第12期2940-2942,共3页
Applied Chemical Industry
基金
重庆市科学技术委员会基础与前沿研究计划(cstc2014jcyjA2/30017)
山区桥梁与隧道工程国家重点实验室培育基地(重庆交通大学)开放基金(CQSLBF-Y15-6,CQSLBF-Y14-5)
国家内河航道整治工程技术研究中心(重庆交通大学)开放基金(SLK2013A03)
交通土木工程材料国家和地方联合工程实验室开放基金(LHSYS-2014-005)
重庆交通大学实验教学改革与研究基金重点项目(Syj201703)
关键词
氧化亚铜纳米线
氧化锌
硫化镉
光催化
cuprous oxide nanowires
zinc oxide
cadmium sulfide
photocatalysis