摘要
硼是一种重要的类金属元素,与人类生活息息相关。自从硼元素被引入到有机化合物中,化学家创造新物质的能力得到了革命性的提升。近年来,随着有机硼化学的蓬勃发展,该领域正在吸引越来越多的关注。本文重点介绍了硼元素的起源与结构,有机硼的1,2-迁移化学的特征及具体反应实例。
Boron has shown great importance as a metalloid and is closely concerned with human life. The introduction of boron into organic molecules has deeply revolutionized the ability of creating new substances. With the explosive development of organoboron chemistry, considerable attentions have been drawn into this area. This article mainly introduces the development and structure of boron, the definition and characteristics of 1,2-migration for organoboron compounds together with their specific reaction examples.
作者
胡越
刘超
HU Yue;LIU Chao(State Key Laboratory for Oxo Synthesis and Selective Oxidation,Lanzhou Institute of Chemical Physics,Chinese Academy of Sciences,Lanzhou 730000,P.R.China)
出处
《大学化学》
CAS
2019年第12期39-44,共6页
University Chemistry
基金
国家自然科学基金(21703265,21872156,21802150,21822303,21772020)
江苏省自然科学基金(BK20181194,BK20180247)
关键词
有机硼化学
1
2-迁移
四配位硼
Organoboron chemistry
1,2-Migration
Tetracoordinated boronate