摘要
Urothermal method was firstly used to synthesize zeolitic tetrazolate-imidazolate frameworks. By using 2-imidazolidone hemihydrate(e-urea) as solvent, a new compound, namely ZTIF-17 with GIS topology, has been obtained by mixing 5,6-dimethylbenzimidazole and 5-ethylthiotrazole ligands, and characterized by powder and single-crystal X-ray diffraction, and thermogravimetric(TG) analyses. In addition, ZTIF-17 exhibited strong photoluminescence at room temperature. The result suggests that urothermal method is powerful to construct new kind of porous materials.
Urothermal method was firstly used to synthesize zeolitic tetrazolate-imidazolate frameworks. By using 2-imidazolidone hemihydrate(e-urea) as solvent, a new compound, namely ZTIF-17 with GIS topology, has been obtained by mixing 5,6-dimethylbenzimidazole and 5-ethylthiotrazole ligands, and characterized by powder and single-crystal X-ray diffraction, and thermogravimetric(TG) analyses. In addition, ZTIF-17 exhibited strong photoluminescence at room temperature. The result suggests that urothermal method is powerful to construct new kind of porous materials.
作者
李敏玉
王飞
张健
LI Min-Yu;WANG Fei;ZHANG Jian(Fujian Provincial Key Laboratory of Featured Materials in Biochemical Industry,Fujian Province University Key Laboratory of Green Energy and Environment Catalysis,College of Chemistry and Materials,Ningde Normal University,Ningde 352100,China;State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou 350002,China;State Key Laboratory of Fine Chemicals,Dalian University of Technology,Dalian 116024,China)
基金
Supported by NNSFC(No.21573236)
the State Key Laboratory of Fine Chemicals(No.KF 1804)
the Foundation of Ningde Normal University(No.2018Y04 and 2018Q105)
the Natural Science Foundation of Fujian Province(No.2019J01839)
