摘要
设计不同时间及温度条件对微波胶粉改性沥青进行老化试验,通过沥青三大指标及动态剪切流变试验,分析了微波胶粉改性沥青在热氧老化作用下性能的变化,并建立热老化动力学方程以揭示微波胶粉改性沥青在老化作用下的性能变化规律。研究结果表明:微波胶粉改性沥青在热氧老化作用下,其内部轻质组分大量逸出,同时部分转变为沥青质等重质组分,沥青变得脆硬,高温抗变形能力提高,而温度和时间的提高均会促进沥青老化程度的加深;微波胶粉改性沥青老化过程中仍存在强烈的胶粉溶胀与降解反应,两种作用共同促进了微波胶粉改性沥青180℃特殊的流变性;采用软化点作为老化参数建立的老化动力学方程能够准确模拟微波胶粉改性沥青的老化进程。
Two aging factors such as temperature and time are designed measurementsfor combination to age the MCRMA.A serious of tests including the dynamic shear test and three indexe measurements of asphalt were employed to analyze the properties of aged MCRMA.Through establishing aging kinetic equation,the characteristic of aging of MCRMA were revealed.The results show that the MCRMA of aging is brittleness due to the escape of light components of asphalt and the conversion of heavy components such as resin and asphaltene,by which the performance of deformation resistance of asphalt is increased.The aging temperature and time could accelerate the process of aging.There still exist strong swelling and degradation reaction of rubber powder during the aging process of asphalt,in which the rheological properties of asphalt at 180℃is changed by two kinds of action.The aging kinetics equation with softening point as the aging parameters can well simulate the MCRMA's actual aging process.
作者
张智豪
李波
任小遇
王永宁
ZHANG Zhihao;LI Bo;REN Xiaoyu;WANG Yongning(National and Provincial Joint Engineering Laboratory of Road&Bridge Disaster Prevention and Control,Lanzhou Jiaotong University,Lanzhou 730070,China;Gansu Province Highway Maintenance Engineering Research Center,Gansu Hengda Road and Bridge Group Co Ltd,Lanzhou 730070,China)
出处
《材料科学与工程学报》
CAS
CSCD
北大核心
2019年第6期1001-1007,共7页
Journal of Materials Science and Engineering
基金
国家自然科学基金资助项目(51408287,51668038)
长江学者和创新团队发展计划滚动资助项目(IRT_15R29)
甘肃省杰出青年基金资助项目(1606RJDA318)
甘肃省自然科学基金资助项目(1506RJZA064)
兰州交通大学优秀科研团队资助项目(201606)
关键词
微波胶粉改性沥青
热老化
流变性能
老化动力学方程
microwave crumb rubber modified asphalt
thermal ageing
rheological property
aging kinetic equation