摘要
The performance of Ce-OMS-2 catalysts was improved by tuning the fill percentage in the hydrothermal synthesis process to increase the oxygen vacancy density.The Ce-OMS-2 samples were prepared with different fill percentages by means of a hydrothermal approach(i.e.80%,70%,50%and 30%).Ce-OMS-2 with 80%fill percentage(Ce-OMS-2-80%)showed ozone conversion of 97%,and a lifetime experiment carried out for more than20 days showed that the activity of the catalyst still remained satisfactorily high(91%).For Ce-OMS-2-80%,Mn ions in the framework as well as K ions in the tunnel sites were replaced by Ce^4+,while for the others only Mn ions were replaced.O2-TPD and H2-TPR measurements proved that the Ce-OMS-2-80%catalyst possessed the greatest number of mobile surface oxygen species.XPS and XAFS showed that increasing the fill percentage can reduce the AOS of Mn and augment the amount of oxygen vacancies.The active sites,which accelerate the elimination of O3,can be enriched by increasing the oxygen vacancies.These findings indicate that increasing ozone removal can be achieved by tuning the fill percentage in the hydrothermal synthesis process.
The performance of Ce-OMS-2 catalysts was improved by tuning the fill percentage in the hydrothermal synthesis process to increase the oxygen vacancy density.The Ce-OMS-2 samples were prepared with different fill percentages by means of a hydrothermal approach（i.e.80%,70%,50% and 30%）.Ce-OMS-2 with 80% fill percentage（Ce-OMS-2-80%）showed ozone conversion of 97%,and a lifetime experiment carried out for more than20 days showed that the activity of the catalyst still remained satisfactorily high（91%）.For Ce-OMS-2-80%,Mn ions in the framework as well as K ions in the tunnel sites were replaced by Ce4+,while for the others only Mn ions were replaced.O2-TPD and H2-TPR measurements proved that the Ce-OMS-2-80% catalyst possessed the greatest number of mobile surface oxygen species.XPS and XAFS showed that increasing the fill percentage can reduce the AOS of Mn and augment the amount of oxygen vacancies.The active sites,which accelerate the elimination of O3,can be enriched by increasing the oxygen vacancies.These findings indicate that increasing ozone removal can be achieved by tuning the fill percentage in the hydrothermal synthesis process.
基金
supported by the National Key R&D Program of China(Nos.2016YFC0207104,2017YFC0211802,and2016YFC0209305)
the National Natural Science Foundation of China(NSFC)(No.21876191)
the Youth Innovation Promotion Association,CAS(No.2017064)
the Science and Technology Project of the Education Department of Jiangxi Province(No.GJJ151258)
